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on oxidized antimony-containing minerals as energy sources. Under continuous stress from high concentrations of Sb, these ... oxidation, reduction, methylation, mineralization, and bioaccumulation (Li,2017; Figure 1). These mechanisms play a vital role in the geochemical cycle of Sb and also ... that antimony-oxidizing bacteria are widely ...
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Increased demand for gold leads to the search for more gold resources. Most of the gold (+2/3) is obtained from the processing of non-refractory gold ores [].Generally, gold ore is treated by cyanidation, and then gold is recovered by zinc powder cementation, activated carbon adsorption or ion exchange resin adsorption, etc [].However, with the development and utilization of gold-rich ore ...
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The conversion of this data to the amount of dissolution per unit mass at the various solid-liquid ratios (Figure 4 and Table 1) indicated that, during the static immersion, the release of antimony from the blast furnace slag increases gradually with the decrease of the ratio of solid to liquid.The maximum amount of antimony released at the end of trial is 42.13 mg/Kg.
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The major use for antimony is now as a trioxide. exhibits poor conductivity of electricity and heat. It has an atomic for ame-retardants. number of 51, an atomic weight of 122 and a density of 6.697 kg/m3. at 26 C. Antimony metal, also known as regulus, melts at 630 C 2. Occurrence and mineralogy.
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Oxidative dissolution of stibnite (Sb 2 S 3 ), one of the most prevalent geochemical processes for antimony (Sb) release, can be promoted by Sb-oxidizing microbes, which were studied under alkaline and neutral conditions but rarely under acidic conditions.
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USAC determined that their antimony assays were high due to the oxidation/reduction method which also assays the iron content. The deposit is regarded as a jasperoid type with all the elemental signatures of the Carlin Nevada type. Los Juarez Project LOS JUAREZ MINE, QUERETARO, MEXICO
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However, dissolved oxygen and lack of nutrient source in antimony mine drainage inhibit sulfate reducing bacteria activity. Biogenetic iron oxide minerals from iron corrosion by iron-oxidizing bacteria may prove promising for antimony adsorption, while the micro-environment generated from iron corrosion by iron oxidizing bacteria may provide better growth conditions for symbiotic sulfate reducing bacteria.
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Under oxic conditions to slightly reducing conditions, the hydrolytic species Sb(OH)6 -is calculated to be the dominant antimony aqueous species at pH values greater than approximately 2.5. At moderately reducing conditions, antimony speciation is dominated by the hydrolytic species Sb(OH)3º (aq) at pH values from 2 to 12.
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First, a concentrated solution of antimony trichloride goes through an electrolysis process in a solution of hydrochloric acid. In an electrolysis process, there has to be an anode and cathode; Antimony is the anode and either platinum or copper is the cathode. Then, antimony is deposited on the cathode, which can potentially lead to an explosion.
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This process consisting of heating molten antimony sulfide in crucibles with slightly more than the (6) Sb 2 S 3 + 3Fe → 2Sb + 3FeS theoretical amount of fine iron scrap, depends on the ability of iron to displace antimony from molten antimony sulfide. Sodium sulfate and carbon are added to produce sodium sulfide, or slag is added to form a light fusible matte with iron sulfide and to facilitate separation of the metal.
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The purpose of this study is to test the feasibility of using mixed culture of iron and sulfur-oxidizing bacteria for the dissolution of metals from high-grade zinc and lead sulfide ore. Considering that the roll crusher could reduce the ore size to ... Microbial Dissolution of Zn-Pb Sulfide Minerals Using Mesophilic Iron and Sulfur-Oxidizing ...
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Antimonial dust is a by-product of lead smelting and an important material for extracting antimony. A new pyrometallurgical process for producing antimony white from the antimonial dust is reported. The process mainly consists of three steps, which are reduction smelting, alkaline refining, and blowing oxidation.
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Despite the ubiquitous presence of Mn oxides in soils and their oxidizing power toward As (III), their impact on interrelated As, Fe, and Mn speciation under microbially reducing conditions remains largely unknown.
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A 9.53-g sample of stibnite, an ore of antimony, is dissolved in hot, concentrated HCI (aq) and passed over a reducing agent so that all the antimony is in the form Sb (aq). The Sb (aq) is completely oxidized by 43.3 mL of a 0.125 M aqueous solution of KBro, (aq).
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The obtained results show that Zn and K 2 O removals of 85% and 75% were achieved under the following conditions: ozone as an oxidant agent and 0.1 M H 2 SO 4 as an aqueous medium; temperature had no significant effect. The results are supported by thermodynamic diagrams and the possible chemical reactions are mentioned.
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A mixed arsenic-antimony oxide occurs in Nature as the very rare mineral stibioclaudetite. Antimony trisulfide: ... It is different from most pyrotechnic colorants in that it is a reducing agent and not an oxidizing agent. ... Preparations relying on aqueous reactions of barium manganate are an extremely slow process due to the low solubility ...
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performed in oxidizing or reducing conditions. Five Sb mines located in South-Central Spain were considered: La Nazarena, Accesos, Balanzona, Pilar, and Susana mines. Rock samples were analysed by X-ray diffraction, confirming that the main Sb carrier was stibnite (Sb2S3), present in all mines.
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US2627498A US117952A US11795249A US2627498A US 2627498 A US2627498 A US 2627498A US 117952 A US117952 A US 117952A US 11795249 A US11795249 A US 11795249A US 2627498 A US2627498 A US 2627498A Authority US United States Prior art keywords asphalt petrolatum temperature weight hours Prior art date 1949-09-26 Legal status (The legal status is an assumption and is not a legal conclusion.
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A process and method for recovering elemental selenium, selenite or selenate from minerals and selenium salts solutions using a reducing sugar to reduce selenium before precipitating the elemental selenium, selenite and/or the selenate.
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Antimony trichloride is a colorless and soft solid that has a strong odor. Antimony trioxide is a white solid that dissolves a little in water. The other antimony(III) halides all react with water except for antimony trifluoride. +5 compounds are strong oxidizing agents. Antimony pentafluoride is highly reactive, as well as antimony pentoxide.
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a process for separation of antimony and arsenic from a leach solution comprising soluble antimony and arsenic, the process comprising: oxidizing the soluble antimony and arsenic in the leach solution so as to reach an oxidation end point determined by at least one of wavelength monitoring and oxidation reduction potential (orp) monitoring, to .
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as a reducing agent. The antimony recovery was in the range from 66 to 73.81 wt% when the temperature was increased from 650 to 800 °C, respectively. On the other hand, the main primary antimony production starts with the processing of mineral Stibnite (Sb 2 S 3) which is an abundant antimony bearing mineral, and
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Antimony is a chemical element with the symbol Sb (from Latin: stibium) and atomic number 51. A lustrous gray metalloid, it is found in nature mainly as the sulfide mineral stibnite (Sb2S3). Antimony compounds have been known since ancient times and were powdered for use as medicine and cosmetics, often known by the Arabic name kohl. Metallic antimony was also known, but it was erroneously ...
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The present invention is concerned with a process for selectively removing antimony, bismuth, or both, from acidic solution by submitting the solution to oxidizing conditions thereby causing the selective precipitation of antimony and bismuth; filtering precipitated antimony and bismuth; and submitting the oxidized solution to reducing conditions before it is returned to the electrorefining cell.
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the PET bottle production process with a view to minimising levels of acetaldehyde migration (Welle 2018). Also acetaldehyde reducing additives are applied in the preform manufacturing process (see Chapter below). Acetaldehyde reducing additives Traces of acetaldehyde can migrate from the PET bottle wall into natural mineral water.
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Antimony trichloride is a colorless crystalline solid. It is shipped as a solid or liquid solution. It is decomposed slowly by water to hydrochloric acid and antimony oxychloride. Antimony oxychloride is soluble in hydrochloric acid but insoluble in water. It is corrosive to metals and tissue. Hazards What is this information? Reactivity Alerts
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Antimony is a gray porous metal and is mainly found as a mineral sulfide in nature. Antimony compounds have been known since ancient times and have been powdered for use in industries such as medicine and cosmetics. Antimony is a chemical element Semimetallic . The metal type of antimony has a light silver color and is hard and brittle.
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Process Description. The ore after hand sorting will go through coarse crushing and fine crushing, during which the size of mineral should be under 30mm, and screening classification have three size fractions, 8-30mm, 2-8mm, 0-2mm. then the three kind of minerals will go respectively into Jig, and HOT mining Sawtooth Wave Jig to gravity ...
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7th international symposium on high-temperature metallurgical processing : proceedings of a symposium sponsored by the pyrometallurgy committee of the extraction and processing division (epd) of the minerals, metals & materials society (tms) held during tms 2016, 145th annual meeting & exhibition, february 14-18 downtown nashville, tennessee, .
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In general, the background level of antimony in drinking water is typically "not detectable" or "less than 0.001 mg/L" ( Source ), but some waters that are influenced by naturally saline water or sulfide minerals may have higher levels of antimony. For drinking water the maximum contaminant level and the maximum contaminant level goal set by ...
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At moderately reducing conditions, antimony speciation is dominated by the hydrolytic species Sb(OH)3° (aq) at pH values from 2 to 12. The concentrations of antimony in soils and sediments are likely controlled by adsorption reactions, but very little is known about the adsorption/desorption behavior of Sb(V) or Sb(III). Antimony
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1School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, China ... and oxido-reduction of toxic metal ions [8, 10]. Antimony (Sb) is a toxic metalloid in group 15 of the ... new hyper antimony-oxidizing bacterium, which has been previously isolated from contaminated mine soils
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Antimony is not common. It is found about as often as thallium.It is quite easy to get, though and is in many minerals.Antimony is sometimes found as an element, but normally it is found as stibnite, an antimony sulfide mineral.Stibnite is the main ore of antimony. China is the biggest maker of antimony; it makes 84% of all antimony.
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Abstract: This article covers a hydrometallurgical method for processing of a gold-antimony flotation concentrate in alkaline sulfide solutions. Thermodynamic analysis of the reaction stibnite with sulfide sodium and sodium hydroxide was performed.
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First, antimony, tin, and arsenic are removed. Next, gold and silver are removed by adding zinc. The lead is then refined by vacuum removal of zinc. Refining continues with the, addition of calcium and magnesium, which combine with bismuth to form an insoluble compound that is skimmed from the kettle.
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In addition to common metals like copper, lead, zinc, and nickel, a number of other metals such as antimony, bismuth, cadmium, cobalt, mercury, and molybdenum occur as sulfide minerals. In the extraction of metals from sulfides, roasting is applied to achieve different objectives depending on the overall process flow sheet.
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antimony (Sb), a metallic element belonging to the nitrogen group (Group 15 [Va] of the periodic table). Antimony exists in many allotropic forms (physically distinct conditions that result from different arrangements of the same atoms in molecules or crystals). Antimony is a lustrous silvery bluish white solid that is very brittle and has a flaky texture. It occurs chiefly as the gray sulfide ...
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Arsenite (As(III)) oxidation has important environmental implications by decreasing both the mobility and toxicity of As in the environment. Microbe-mediated nitrate-dependent As(III) oxidation (NDAO) may be an important process for As(III) oxidation in anoxic environments. Our current knowledge of nitrate-dependent As(III)-oxidizing bacteria (NDAB), however, is largely based on isolates, and ...
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The objectives of this study were to combine biogeochemistry along with metagenomics to: (1) demonstrate the potential for Sb (V) reduction coupled to S oxidation, (2) elucidate the identity and...
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of 3 Wt.% coke at reduction temperatures of 840-870 °C yields a slag phase containing 60 to 65 Wt.% Sb2O3 and a metal phase containing not more than 5 Wt.% antimony. To validate temperatures and coke addition, thermochemical modelling of the reduction process was executed using FactSage™ 6.4.
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